When I saw the start of this, I was hoping I'd have some good news - hoping the PI motor was the same as the 429CJ/SCJ motor. A guy I knew in the mid-1970s had one, and it moved out sharply. But that was only in 1971.
For TedIII, you're right for cars like yours and mine - the shock towers are too close for the 429/460 motors without some shock tower surgery. 1971, with the big body, was the first year that would take the 429 without it. That's where KarKraft made their name with the Boss 429 in 1969/1970 - fixing the width of the engine bay. And with crescent heads, the plugs were right up on top where you could actually change them.
Back to the question at hand. The 429CJ/SCJ heads look like they were D0OE-R, with screw-in rocker studs and factory guide plates. The block would be the D0VE-A block, and the SCJ had the four-bolt mains. They ran 11.3:1 compression, but the later ones would be lower.
I have only limited specs on the 429 police engine, but it should have D2OE-AB heads. 89cc chambers, 2.08 intake/1.66 exhaust valves, 1.65x2.19 intake, 1.47x2.06 exhaust ports.
The D0OE-R heads are much better for making power. 73.5cc chambers, 2.24 intake/1.72 exhaust valves, 2.12x2.56 intake/1.32x2.24 exhaust ports.
That's all I've got on these. Good luck - the 429 will bolt in with the right motor mounts, and the C6 is plenty tough. Don't know what rear end you've got - could be the weak link, both in terms of handling power, and (if it's an open diff) traction.